Maybe the Interfaith Hospitality Network, a local nonprofit that helps families who have lost their housing. [Edited to add] Often that's due to fire, so that they've lost most of their belongings as well.
Career Gear is one. Another option if it's practical is to store until Morrow's Turnover sale.
Bin donations typically are shredded, as are most donations through organizations that pick up.
POst mortem - wife found "Green Drop" which gladly accepted my business shirts, suits, sports coats and wool pants. Hopefully they find a good home for them.
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Rather than dry clean and put my clothes in one of those outlot donation bins, I figure there's probably a decent organization that re-purposes gently-used wool pants, suits, sport coats and shirts for men entering the professional workforce. Any ideas?